It is greyed out because the theme sets it itself. So you have to look on the theme pages. We have a lot of functions to set the sizes on the layout which - as said - override any options. There are various layout reasons why you would want to do that, one would be responsive behavior which often works with columns so the sizes cannot be changed.
I still think there's something overriding the theme, unless I'm totally clueless (which very well could be the case). Everything in functions.php, themeoptions.php, and so on for zpMasonry shows the album thumbs should be more than 100px, yet on album view, I'm only getting 100px using:
``