I have looked around for some time about charset in Lightroom and as far as people say it is not possible to change it. They have complained ever since Lightroom was in Beta and now it is 2.x and nothing has changed and no feedback from Adobe what so ever about it.
I have been told by a photographer not to use bridge for any IPTC related things, it can really screw up the data. I might give it a try and see how it goes.
To mention Lightroom, even on the PC you are not able to write any of the áéóÃú letters in the program they turn out as ´a´e´o´i´u. However you can paste them in from Text edit for example. It really pisses the Scandinavians off. EDIT: Hold that thought I have just been reported Adobe finally fixed that problem with version 2.2, about freaking time.
Why is Charset such a hassle, hehe.