Ok... I found out why it isn't working, hopefully it makes sense to you guys.
First I tried adding the CR2 without the dot and hitting enter, then save. This doesn't "seem" to work, but when I checked the database I noticed it was being added with a value of 0.
AnyFile_file_list_CR2 0 NULL NULL
I changed it to 1 in the database and it shows on the list and it lets me upload CR2 files.
AnyFile_file_list_CR2 1 NULL NULL
Hopefully this helps `